4/29/2023 0 Comments Krypton solutions![]() Things like employees hired before HR even knew or processed any paperwork, sometimes with the employee having already started.Īll of this saddens me because the possibility of Krypton to become something great is possible but they can’t allow delegation to actually happen. They tried to fix this multiple times but each time it still happens. Policies routinely ignored by management but supposed to be enforced for the average employee. I’ve seen members of management get upset they have to do so much but they don’t allow the employees the latitude to get the job done. ![]() Often they are treated as if they don’t know anything or that they can’t do their jobs. ![]() They hire people do do a job but then don’t trust them to actually do their jobs. Management play’s favorites sometimes, but the biggest issue is the micromanagement. Finally when they did, it seemed only by force. I have been there for a number of years and during that time I always saw Krypton grow to a certain point but never make it over that point. The drive and culture there can achieve much more than they are right now. Krypton could be much better than it currently is. How you gonna grow a company and you don’t trust the employees that are supposed to do the job they’re supposed to do? They talk about common sense. They ask you to do more and more instead of making the system better. People would leave left and right because of the pay and other things. After a great year, people still got almost nothing for bonus. They should be in the back somewhere and never get out of there. No communication skills and listening skills of any kind. They put people in place in management that should not be. Even if it’s not your fault they’ll find a way to make it yours. They are stubborn to the point where people with great ideas don’t even get listened to. Meaning your word versus theirs guess who wins? You can never get an idea across even if it will better the company. The same people that run things is the same people that own the company. They do not obey the regular structure of you go up and you get paid more. ![]() The spectroscopic and theoretical results are compared to the corresponding properties for some similar molecules.It’s a great company with great flexibility but there are a few things off that you will notice as you go. Comparisons are made with the parameters obtained for some other molecules containing the FCH2 group. By combining previously reported rotational constants for the C2 and C1 conformers with ab initio MP2/6-311 + G(d, p) predicted parameters, adjusted r0 parameters have been obtained for both conformers. A complete vibrational assignment is proposed for the C2 conformer and many of the fundamentals have been identified for the C1 form based on the force constants, relative intensities and rotational-vibrational band contours obtained from the predicted equilibrium geometry parameters. The B3LYP calculations predict a better energy difference for both the C1 and C2v as well as for the Cs conformers than the MP2 values. The MP2 calculations predict the C1 conformer stability to be slightly higher than the experimentally determined value whereas for the C2v and Cs conformers the predicted energy difference is much larger than the experimental value. Equilibrium geometries and total energies of the four stable conformers have been determined from ab initio calculations with full electron correlation by the perturbation method to second order as well as by hybrid density functional theory calculations with the B3LYP method using a number of basis sets. It is estimated that there is 64 +/- 3% of the C2 form, 34 +/-3% of the C1 form, 1% of the C2v form and 0.6% of the Cs conformer present at ambient temperature. By utilizing six pairs of fundamentals for these two conformers in the krypton solutions, an enthalpy difference of 277 +/- 28 cm(-1) (3.31 +/- 0.33 kJ mol(-1)) has been obtained for the C2 versus C1 conformer with the C2 conformer the more stable form. C2v (trans-trans) and Cs (gauche-gauche'). Tentative assignments have been made for a few of the fundamentals of the other two conformers, i.e. From a comparison of the spectra of the fluid phases with that in the solid, all of the fundamental vibrations of the C2 conformer (gauche-gauche) where the first gauche indicates the form for one of the CH2F groups and the second gauche the other CH2F, and many of those for the C1 form (trans-gauche) have been identified. Additionally, the infrared spectra (3200-50 cm(-1)) of the gas and solid have been recorded as well as the Raman spectrum of the liquid. The infrared spectra (3200-400 cm(-1)) of krypton solutions of 1,3-difluoropropane, FCH2CH2CH2F, at variable temperatures (-105 to -150 degrees C) have been recorded.
0 Comments
Leave a Reply. |
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |